Overviews from our group Tantillo, D. J. American Scientist 2019, 107, 22-23: "Wiggling and Jiggling" Hare, S. R.; Tantillo, D. J. Pure Appl. Chem. 2017, 89, 679-698: "Post-Transition State Bifurcations Gain Momentum – Current State of the Field” Hare, S. R.; Tantillo, D. J. Beilstein J. Org. Chem. 2016, 12, 377-390: "Dynamic Behavior of Rearranging Carbocations – Implications for Terpene Biosynthesis" (correction: Beilstein J. Org. Chem. 2017, 13, 1669-1669)
Representative examples of research studies on reaction dynamics from our group Campos, R. B.; Tantillo, D. J. Chem 2019, 5, 227-236: "Designing Reactions with Post-Transition State Bifurcations: Asynchronous Nitrene Insertions into C–C sigma-Bonds” Castineira Reis, M; Silva Lopez, C.; Faza, O. N.; Tantillo, D. J. Chem. Sci. 2019, 10, 2159-2170: "Pushing the Limits of Concertedness. A Waltz of Wandering Carbocations” Hare, S. H.; Li, A.; Tantillo, D. J. Chem. Sci. 2018, 9, 8937-8945: "Post-Transition State Bifurcations Induce Dynamical Detours in Pummerer-Like Reactions” Blumel, M.; Nagasawa, S.; Blackford, K.; Hare, S. R.; Tantillo, D. J.; Sarpong, R. J. Am. Chem. Soc. 2018, 140, 9291-9298: "Rearrangement of Hydroxylated Pinene Derivatives to Fenchone-Type Frameworks: Computational Evidence for Dynamically-Controlled Selectvity” Hare, S. R.; Pemberton, R. P.; Tantillo, D. J. J. Am. Chem. Soc. 2017, 139, 7485-7493: "Navigating Past a Fork in the Road—Carbocation–π Interactions Can Manipulate Dynamic Behavior of Reactions Facing Post-Transition State Bifurcations” Hare, S. R.; Tantillo, D. J. Chem. Sci. 2017, 8, 1442-1449: "Cryptic Post-Transition State Bifurcations Reduce the Efficiency of Lactone-Forming Rh-Carbenoid C-H Insertions” Pemberton, R. P.; Tantillo, D. J. Chem. Sci. 2014, 5, 3301-3308: "Lifetimes of Carbocations Encountered along Reaction Coordinates for Terpene Formation" Hong, Y. J.; Tantillo, D. J. Nature Chem. 2014, 6, 104-111: "Biosynthetic Consequences of Multiple Sequential Post-Transition State Bifurcations"
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